Advanced applications of Zr-based MOFs in the removal of water pollutants

The global water pollution is caused by the increase of industrial and agricultural activities, which have produced various toxic pollutants. Pollutants in water generally consist of metal ions, pharmaceuticals and personal care products (PPCPs), oil spills, organic dyes, and other organic pollutants. Amongst the adsorbents that have been developed to deal with pollutants in water, Zr-based metal-organic frameworks (MOFs) have drawn scientists' great attention due to their excellent stability and adjustable functionalization. Herein, the present review article introduces the synthetic methods of functionalized Zr-based MOFs and summarizes their applications in water pollution treatment. It also clarifies the interactions and removal mechanisms between pollutants and Zr-based MOFs. The use of these MOFs with eminent adsorption ability and recycling performance have been discussed in detail. Zr-based MOFs also face some challenges such as high cost, lack of real water environment applications, selective removal of pollutants, and low ability to remove composite pollutants. Future research should focus on addressing these issues. Although there is still a blank of the practical utility of Zr-based MOFs on a commercial scale, the research reported to date clearly shows that they are very promising materials for the water treatment.