Antimonate removal by diatomite modified with Fe-Mn oxides: application and mechanism study

In this study, diatomite coated with Fe-Mn oxides (DFMO) was synthesized through calcination. The adsorption of antimonate (Sb(V)) by DFMO was studied, and environmental factors affecting the adsorption were investigated. The components of DFMO were identified as γ-Fe₂O₃, γ-MnO₂, and SiO₂, in the presence of diatomite covered with nanoscale metal oxides. Batch experiments were carried out to evaluate the antimonate adsorption performance in aqueous solution. Results showed that maximum Sb(V) adsorption capacity of DFMO reached 10.7 mg/g at pH 4, corresponding to 22.2 mg/g per unit metal oxides. Antimonate adsorption occurred on heterogenous surface, following the Freundlich and Pseudo-second order model. Overall, antimonate adsorption was favored at acidic condition due to low point of zero charge. However, when treating electroplating wastewater, neutral pH condition exhibited a higher efficiency than acidic pH, because co-existing ions in electroplating wastewater significantly affects antimony adsorption. Further investigation showed that among different potential co-existing ions, fluoride can strongly inhibit the adsorption of antimonate at 5 mg/L under pH 4. Density functional theory (DFT) analysis confirmed that adsorption energy on DFMO follows: HF < F^- < Sb(OH)₆^-, indicating that fluoride is easier to bind with DFMO compared to antimonate, especially under pH 3.5 at which fluoride exists as HF. Moreover, the competitive adsorption of fluoride toward antimonate indicated the necessity of pre-treatment like neutralization and precipitation before adsorption process.