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Published on: January 7, 2019
On-Site Fluorination for Enhancing Utilization of Lithium in a Lithium-Sulfur Full Battery
1Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China.
Abstract:
The rechargeability of the lithium anode in lithium-sulfur (Li-S) batteries is an issue for this type of battery. In this work, we demonstrate a Li-S full battery comprising a protected anode scaffold and a Li2S cathode. The stabilized performance is attained by an on-site fluorination strategy, using BiF3 for the interfacial coating of the anode. Unlike previously reported LiF protective coating derived from the vapor/solution depositions, BiF3 nanocrystals would be lithiated on-site to the anode surface and server as the protective layer. The chemically inertial Li3Bi alloy can provide additional ion-conductive paths and stitch the LiF to form a seamless protective layer, thereby suppressing the dendrite propagation and parasitic reactions effectively. With the designed anode structures and compositions, the high-loading full battery (8.05 mg cm-2) can achieve an exceptional utilization of both sulfur (898 mAh gS-1) and lithium (1533 mAh gLi-1) over 200 cycles, marking a step toward cyclable Li metal batteries at a high capacity.
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