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Updated: Nov 29, 2025

Molecular Entanglement and Electrospinnability of Biopolymers
Published on: September 3, 2014
Critical overlap concentration and intrinsic viscosity data of xanthan gum aqueous solutions in dimethyl sulfoxide
Tomás Rodrigues1, Francisco J Galindo-Rosales2, Laura Campo-Deaño1
1Centro de Estudos de Fenómenos de Transporte (CEFT), Departamento de Engenharia Mecânica, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, s/n, Porto 4200-465, Portugal.
Abstract:
This is the supplementary information of the research paper "Haemodynamics around confined microscopic cylinders" by Rodrigues et al. [1]. The critical overlap concentration of entanglement of polymer coils indicates whether a polymer solution is dilute or semidilute. Here, the reader will find the determination of for xanthan gum aqueous solutions in 52 wt.% of dimethyl sulfoxide, often used as non-particulate blood analogues. From the shear flow curves of a dilution series of the polymer the zero-shear viscosities were obtained, allowing us to estimate the intrinsic viscosity based on the xanthan gum concentration of the fluids. Two methodologies for doing so are described: using information from multi-concentration measurements and from a single polymer solution (rough estimate). With the intrinsic viscosity the determination of is straightforward.
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