Influence of Antimony Oxide on Epoxy Based Intumescent Flame Retardation Coating System

Ethylenediamine modified Ammonium polyphosphate (EDA-MAPP), and Charring-Foaming Agents (CFA) was prepared via a simple chemical approach and further utilizes for the preparation of Epoxy resin based intumescent flame retardation coatings. The ratio belongs to MAPP and CFA was fixed at 2:1 ratio. Comparative thermo gravimetric analysis TGA study of Modified Ammonium polyphosphate (MAPP) and Ammonium polyphosphate (APP) investigated. Sb₂O₃ was introduced into flame retardation coating formulation at various amounts to evaluate the synergistic action of Sb₂O₃ along with flame retardant coating system. The synergistic action of Sb₂O₃ on flame retardation coating formulation was studied by vertical burning test (UL-94V), thermo gravimetric analysis (TGA), Limited Oxygen Index (LOI), and Fourier Transform Infra-Red spectroscopy (FTIR). The UL-94V results indicated that adding Sb₂O₃ effectively increased flame retardancy and meets V-0 ratings at each concentration. The TGA results revealed that the amalgamation of Sb₂O₃ at each concentration effectively increased the thermal stability of the flame retardant coating system. Cone-calorimeter study results that Sb₂O₃ successfully minimized the combustion parameters like, Peak Heat Release Rate (PHRR), and Total Heat Release (THR). The FTIR result shows that Sb₂O₃ can react with MAPP and generates the dense-charred layer which prevents the transfer of heat and oxygen.