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Updated: Nov 29, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
A polyoxometalate-encapsulated nanocage cluster organic framework built from {Cu4P2} units and its efficient
Shaobin Li1, Xiaoguo Tan, Ming Yue
1College of Materials Science and Engineering, Key Laboratory of Polymeric Composite Materials of Heilongjiang Province, Qiqihar University, Qiqihar 161006, P. R. China. qqhrlsb1022@126.com zhangli10227@126.com.
Abstract:
The first polyoxometalate (POM)-encapsulated twenty-four-nucleus organophosphorus-copper nanocage cluster organic framework has been constructed. Here, the phosphomolybdate POMs were incorporated into an octahedral nanocage cluster organic framework, and the resulting material exhibited highly efficient bifunctional electrochemical performance. The crystalline material showed a high specific capacitance of 366.3 F g-1 at a current density of 3 A g-1.

