Related Experiment Video
Updated: Nov 29, 2025

Preparation, Purification, and Characterization of Lanthanide Complexes for Use as Contrast Agents for Magnetic Resonance Imaging
Published on: July 21, 2011
Slow relaxation of magnetization in lanthanide-biradical complexes based on a functionalized nitronyl nitroxide
1Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi 435002, P. R. China. sunjuan@hbnu.edu.cn.
Abstract:
Three novel lanthanide-biradical complexes {[Ln(hfac)3]2(mbisNITPyPh)(H2O)}{[Ln(hfac)3](mbisNITPyPh)}·CHCl3 (1-Gd; 2-Tb; 3-Dy) were successfully achieved by reacting the biradical mbisNITPyPh (5-(3-pyridyl)-1,3-bis(1-oxyl-3'-oxido-4',4',5',5'-tetramethyl-4,5-hydro-1H-imidazol-2-yl)benzene) with Ln(hfac)3·2H2O (hfac = hexafluoroacetylacetonate). These Ln-biradical complexes consist of two kinds of spin moieties, namely, dinuclear {[Ln(hfac)3]2(mbisNITPyPh)(H2O)} and mononuclear {[Ln(hfac)3](mbisNITPyPh)}, in which two adjacent dinuclear units are linked by intermolecular hydrogen bonds involving the uncoordinated nitroxide units and the coordinated water molecules of Ln ions, forming a cyclic tetranuclear structure unit. The magnetization study reveals that intramolecular Ln(iii)-coordinated NO ferromagnetic interactions are dominant in the present system. Moreover, the clear frequency dependence of ac magnetic susceptibilities of complex 3-Dy is indicative of slow relaxation of magnetization behavior, indicating its single-molecule magnet nature.
More Related Videos
09:38Fabrication Procedures and Birefringence Measurements for Designing Magnetically Responsive Lanthanide Ion Chelating Phospholipid Assemblies
Published on: January 3, 2018
08:01Rapid Scan Electron Paramagnetic Resonance Opens New Avenues for Imaging Physiologically Important Parameters In Vivo
Published on: September 26, 2016
Related Concept Videos
Atomic Nuclei: Nuclear Relaxation Processes
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers...
Valence Bond Theory
Atomic Nuclei: Magnetic Resonance
Electron Paramagnetic Resonance (EPR) Spectroscopy: Organic Radicals