Design of Surfactant Tails for Effective Surface Tension Reduction and Micellization in Water and/or Supercritical...

The interfacial properties and water-in-CO₂ (W/CO₂) microemulsion (μE) formation with double- and novel triple-tail surfactants bearing trimethylsilyl (TMS) groups in the tails are investigated. Comparisons of these properties are made with those for analogous hydrocarbon (HC) and fluorocarbon (FC) tail surfactants. Surface tension measurements allowed for critical micelle concentrations (CMC) and surface tensions at the CMC (γ_CMC) to be determined, resulting in the following trend in surface activity FC > TMS > HC. Addition of a third surfactant tail gave rise to increased surface activity, and very low γ_CMC values were recorded for the double/triple-tail TMS and HC surfactants. Comparing effective tail group densities (ρ_layer) of the respective surfactants allowed for an understanding of how γ_CMC is affected by both the number of surfactant tails and the chemistry of the tails. These results highlight the important role of tail group chemical structure on ρ_layer for double-tail surfactants. For triple-tail surfactants, however, the degree to which ρ_layer is affected by tail group architecture is harder to discern due to formation of highly dense layers. Stable W/CO₂ μEs were formed by both the double- and the triple-tail TMS surfactants. High-pressure small-angle neutron scattering (HP-SANS) has been used to characterize the nanostructures of W/CO₂ μEs formed by the double- and triple-tail surfactants, and at constant pressure and temperature, the aqueous cores of the microemulsions were found to swell with increasing water-to-surfactant ratio (W₀). A maximum W₀ value of 25 was recorded for the triple-tail TMS surfactant, which is very rare for nonfluorinated surfactants. These data therefore highlight important parameters required to design fluorine-free environmentally responsible surfactants for stabilizing W/CO₂ μEs.