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Published on: December 27, 2018
Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based
Ryo Inoue1, Riki Kondo, Yasuhiro Morisaki
1Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan. ymo@kwansei.ac.jp.
Abstract:
An optically active binuclear platinum(ii) complex based on planar chiral [2.2]paracyclophane was synthesized. The corresponding enantiomers exhibited red circularly polarized phosphorescence (CPP) with the dissymmetry factor |glum| = 1.0 × 10-3. We report, for the first time, theoretical estimation of the CPP |glum| value using relativistic calculations.
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