Mechanical and Durability Performance Improvement of Natural Hydraulic Lime-Based Mortars by Lithium Silicate...

Natural hydraulic lime (NHL) as a building material has been widely used to restore the historic structure. However, the slow growth rate of strength and durability limits its engineering application. In this work, the NHL-based mortars were pretreated by lithium silicate (LS) solution impregnation and surface spraying. The results show that the compressive strength, surface hardness, and freeze-thaw cycle (FTC) resistance of NHL-based mortar were greatly improved after LS pretreatment. Specifically, the compressive strengths of the sample increased by about 32.7-52.0%. LS was sprayed on the sample's surface (about 0.2 kg/m²) and the surface hardness increased by up to 10 grades. Compared with the control samples, the weight loss of treated samples decreased by about 31.6-43.8%. A rehydration process to generate the hydrated calcium silicate gel (C-S-H) was observed between calcium hydroxide (CH) and LS, which can decrease the sample's porosity and form a silicate coating on the surface. With an increase in the concentration of LS, the macropores (50-10,000 nm) content decreased, while the mesopores (10-50 nm) and nanopores (less than 10 nm) increased. This work reveals that the LS pretreatment provides a potential route to improve NHL-based mortar's mechanical properties and durability.