Precious and critical metals from wasted LED lamps: characterization and evaluation

LED lamps already conquered the market of general lighting and are expected to generate a substantial stream of e-waste in the coming years. The challenge of recycling LED lamps have emerged, and it is essential to address both environmental and economic aspects to achieve a circular economy. LED lamps contain precious and critical metals, which can be found in electrical components and in the LED itself, making them a prospective waste for recycling initiatives. However, data about the concentration and distribution of these metals in the LED lamp's components are still scarce and uncertain. This work aims to characterise the various components of different brands of LED lamps to provide novel data on the precious and critical metals' amounts. Gold and silver were found in all brands of lamp, and we highlight the occurrence of gold in all analysed components, in concentrations between 0.01% and 0.07%, which is relevant to the economic viability of future recycling routes (gold and silver can contribute with USD 4340.00 per ton of LED lamps). The critical metals gallium, yttrium, and cerium were found in LEDs, while cobalt, barium, gallium, antimony, and manganese were found in printed circuit boards (PCBs). Additionally, the elements lead, cadmium, and arsenic were characterised due to their association with environmental and human toxicity.