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Updated: Nov 28, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
A functionalized metal organic framework-laden nanoporous polymer electrolyte for exceptionally stable lithium
Xia Qing1, Jiarui Li1, Zongtao Wang2
1Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education and Yunnan Province, School of Chemical Science and Technology, Yunnan University, Kunming, China650091. xrlin@ynu.edu.cn.
Abstract:
A nanoporous all-solid-state MOF-laden polymer electrolyte that is simply mediated by an electronic effect shows remarkably high lithium electrodeposition stability of hundreds of charge-discharge cycles and over 1500 operating hours, while maintaining a very small voltage polarization. This result is a significant improvement relative to conventional PEO and, when used in an all-solid-state battery (ASSB), this electrolyte enabled enhanced cycle life. This new all-solid-state electrolyte shows a promising rational design for the emerging microporous polymeric materials as novel SPEs in ASSBs.

