Hydroxyapatite nanoparticle functionalized activated carbon particle electrode that removes strontium from spiked...

Biohazard performance of Sr radionuclide can be significantly magnified by its release from the contaminated sedimentation. In this study, hydroxyapatite nanoparticle-functionalized activated carbon electrode (AC-HAP) was synthesized and stacked to the cathode compartment of the electrokinetic (EK) system to develop a unipolar three-dimensional (3D) electrochemical process for Sr²⁺ removal from spiked soils. Sr²⁺ adsorption by AC-HAP can be fitted by the pseudo-first-order and pseudo-second-order kinetic models and the Langmuir, Freundlich, and Temkin isotherm models. The largest monolayer adsorption capacity of AC-HAP of 69.49 mg g^-1 was evaluated in the pH range of 10-12 and at 40 °C. 3D EK further intensified the adsorption process of AC-HAP and the corresponding Sr²⁺ removal from aqueous environments. Voltage gradients and proposing time had a significant effect on the migration and transmission of Sr²⁺ in the electrolyzer. The influence of competitive ions on Sr²⁺ removal in the stock solutions followed Al³⁺ < Mg²⁺ < K⁺ < Na⁺ < Ca²⁺ while followed Al³⁺ < Na⁺ < K⁺ < Mg²⁺ < Ca²⁺ in 3D EK. The first three cycles for AC-HAP had taken roughly 50% of the reusability percentage. Sr²⁺ removal from spiked samples in 3D EK was achieved by acid dissolution, electromigration, and selective uptake on particle electrode.