Promoted oxidation of polycyclic aromatic hydrocarbons in soils by dual persulfate/calcium peroxide system

In situ chemical oxidations (ISCO) have been demonstrated as effective ways for remediating soils contaminated with organic pollutants by complete mineralization. This work aims to develop a technology for the oxidation remediation of soils contaminated with Polycyclic Aromatic Hydrocarbons (PAHs) using a dual calcium peroxide (CP)/persulfate (PS) oxidant system activated by oxalic acid (OA)-chelating Fe²⁺. The dual peroxide system was set up, and the effects of 5 single factors (i.e., CP dosage, PS dosage, Fe²⁺ dosage, OA concentration, and soil/water ratio) on PAHs degradation were studied using the single-factor experiment. The response surface method was then introduced to obtain the optimized experimental conditions (CP dosage, PS dosage, OA concentration) of the dual peroxide system. The result shows that the dual peroxide system significantly increased the PAHs degradation and the maximum PAHs degradation efficiency (70.8%) was achieved by the dual peroxide system under optimal conditions (PS dosage, CP concentration, Fe²⁺/PS ratio, and Fe²⁺/OA ratio was 8.89 g/kg, 0.18 mol/L, 1/4 and 0.62) at neutral soil condition. This study is an illustration of the promising efficiency of the dual peroxide system for PAH oxidation in the neutral soil and has great potential for remediation of PAHs contaminated farmland soils.