Hydrogen Peroxide Emission and Fate Indoors during Non-bleach Cleaning: A Chamber and Modeling Study

Activities such as household cleaning can greatly alter the composition of air in indoor environments. We continuously monitored hydrogen peroxide (H₂O₂) from household non-bleach surface cleaning in a chamber designed to simulate a residential room. Mixing ratios of up to 610 ppbv gaseous H₂O₂ were observed following cleaning, orders of magnitude higher than background levels (sub-ppbv). Gaseous H₂O₂ levels decreased rapidly and irreversibly, with removal rate constants (k_H) 17-73 times larger than air change rate (ACR). Increasing the surface-area-to-volume ratio within the room caused peak H₂O₂ mixing ratios to decrease and k_H to increase, suggesting that surface uptake dominated H₂O₂ loss. Volatile organic compound (VOC) levels increased rapidly after cleaning and then decreased with removal rate constants 1.2-7.2 times larger than ACR, indicating loss due to surface partitioning and/or chemical reactions. We predicted photochemical radical production rates and steady-state concentrations in the simulated room using a detailed chemical model for indoor air (the INDCM). Model results suggest that, following cleaning, H₂O₂ photolysis increased OH concentrations by 10-40% to 9.7 × 10⁵ molec cm^-3 and hydroperoxy radical (HO₂) concentrations by 50-70% to 2.3 × 10⁷ molec cm^-3 depending on the cleaning method and lighting conditions.