Methylene Blue Dye Photocatalytic Degradation over Synthesised Fe₃O₄/AC/TiO₂ Nano-Catalyst: Degradation and...

In this study, activated carbon (AC) from coconut shell, as a widely available agricultural waste, was synthesised in a simple one-step procedure and used to produce a magnetic Fe₃O₄/AC/TiO₂ nano-catalyst for the degradation of methylene blue (MB) dye under UV light. Scanning electron microscopy revealed that TiO₂ nanoparticles, with an average particle size of 45 to 62 nm, covered the surface of the AC porous structure without a reunion of its structure, which according to the TGA results enhanced the stability of the photocatalyst at high temperatures. The photocatalytic activities of synthesised AC, commercial TiO₂, Fe₃O₄/AC, and Fe₃O₄/AC/TiO₂ were compared, with Fe₃O₄/AC/TiO₂ (1:2) exhibiting the highest catalytic activity (98%). Furthermore, evaluation of the recovery and reusability of the photocatalysts after treatment revealed that seven treatment cycles were possible without a significant reduction in the removal efficiency.