Related Experiment Video
Updated: Nov 27, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Thermodynamically Constrained Averaging Theory: Principles, Model Hierarchies, and Deviation Kinetic Energy
Cass T Miller1, William G Gray1, Christopher E Kees2
1Department of Environmental Sciences and Engineering, University of North Carolina, Chapel Hill, NC 27599-7431, USA.
The thermodynamically constrained averaging theory (TCAT) provides consistent, thermodynamically sound models for multiphase, multiscale systems. This work enhances TCAT accessibility and extends it for complex flows like turbulent multiphase systems.
Area of Science:
- Multiphase flow modeling
- Thermodynamics
- Continuum mechanics
Background:
- Hierarchical models are crucial for multiphase, multiscale systems.
- The thermodynamically constrained averaging theory (TCAT) offers a robust framework for developing these models.
- Existing TCAT applications can be complex to formulate.
Purpose of the Study:
- To make the thermodynamically constrained averaging theory (TCAT) more accessible for practical applications.
- To extend TCAT to include deviation kinetic energy for broader applicability.
- To enable higher-fidelity models for complex systems like turbulent multiphase flows.
Main Methods:
- Formulating hierarchies of models based on the second law of thermodynamics.
- Utilizing existing TCAT components to reduce formulation effort.
- Extending TCAT by incorporating deviation kinetic energy and associated equations.
Main Results:
- TCAT ensures thermodynamic consistency across disparate length scales.
- A structured approach to model building is inherent in TCAT.
- The inclusion of deviation kinetic energy expands TCAT's applicability to flows beyond slow porous media.
Conclusions:
- TCAT provides a powerful, consistent framework for multiphase, multiscale modeling.
- Simplifying TCAT application accelerates the development of advanced models.
- The extended TCAT is suitable for high-fidelity simulations of complex fluid dynamics.
Related Concept Videos
Kinetic Molecular Theory: Molecular Velocities, Temperature, and Kinetic Energy
Basic Postulates of Kinetic Molecular Theory: Particle Size, Energy, and Collision
Kinetic Energy for a Rigid Body
Energy Diagrams - I
Take the example of a skater on a parabolic ramp. The potential energy at different points along the ramp will be proportional to the height of the ramp, which varies quadratically with the horizontal position on the ramp. As the skater moves down the ramp from the highest position,...
Thermodynamic Systems
Consider an example of tea boiling in a kettle. The...
Entropy and the Second Law of Thermodynamics
The relation between entropy and disorder can be illustrated with the example of the phase change of ice to water. In ice, the molecules are located at specific sites giving a solid state, whereas, in a liquid form, these molecules are much freer to move. The molecular arrangement has therefore become more randomized. Although the change in average...

