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Updated: Nov 27, 2025

Characterization of Thermal Transport in One-dimensional Solid Materials
Published on: January 26, 2014
Thermally Conductive Polyethylene/Expanded Graphite Composites as Heat Transfer Surface: Mechanical, Thermo-Physical
Patrik Sobolčiak1, Asma Abdulgader1, Miroslav Mrlik2
1Center for Advanced Materials, Qatar University, P.O. Box 2713 Doha, Qatar.
High-density polyethylene (HDPE) and expanded graphite (EG) composites show enhanced thermal conductivity and surface wettability for desalination heat exchangers. Plasma treatment improves performance and fouling resistance, approaching stainless steel efficiency.
Area of Science:
- Materials Science
- Chemical Engineering
- Polymer Science
Background:
- Desalination technologies require efficient and durable heat exchangers.
- High-density polyethylene (HDPE) composites offer potential but require property enhancement.
- Expanded graphite (EG) can improve thermal conductivity in polymer composites.
Purpose of the Study:
- To develop and characterize HDPE/EG composites for multi-effect distillation (MED) desalination heat exchangers.
- To investigate the effect of EG loading and plasma treatment on composite properties.
- To evaluate the performance and fouling resistance of the developed composites.
Main Methods:
- Preparation of HDPE/EG composites with varying EG content.
- Characterization of thermal conductivity, surface wettability (surface free energy), and viscoelastic properties.
- Application of corona and radio frequency (RF) plasma treatments.
- Assessment of overall heat transfer coefficient and crystallization fouling resistance.
Main Results:
- A 372% increase in thermal conductivity was achieved at 50 wt.% EG loading.
- Plasma treatment significantly enhanced surface wettability and retained it over two months.
- Processing techniques (extrusion vs. injection molding) were optimized based on EG content (below/above 30 wt.%).
- Plasma-treated composites achieved 98% of stainless steel's heat transfer coefficient and showed superior fouling resistance.
Conclusions:
- HDPE/EG composites are promising materials for desalination heat exchangers.
- Plasma treatment effectively enhances surface properties and fouling resistance.
- Optimized composite formulations and processing methods are crucial for efficient heat exchange applications.
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