Synthesis of raspberry-like antimony-platinum (SbPt) nanoparticles as highly active electrocatalysts for hydrogen...

Binary transition metals can facilitate the hydrogen evolution reaction (HER) through the synergistic integration of different electrochemical properties. To determine binary transition metals that are highly active, Greely et al. conducted a simulation of 256 different binary transition metals. They demonstrated that BiPt, PtRu, AsPt, SbPt, BiRh, RhRe, PtRe, AsRu, IrRu, RhRu, IrRe, and PtRh could be used as efficient electrocatalysts for HER. However, only few of them are synthesized and used as electrocatalysts. In this work, we report the synthesis of the raspberry-like antimony-platinum (SbPt) nanoparticles (NPs) via a colloidal nanocrystal synthesis. These NPs exhibited efficient activity with a low overpotential of 27 mV to reach 10 mA cm^-2 in acidic media. We conducted long-term durability test for 90,000 s under an applied voltage of 0.5 V (vs. RHE) and cycling tests of over 10,000 cycles under an applied voltage of 0.1 to -0.5 V (vs. RHE). The high activity exhibited by the raspberry-like SbPt NPs may be due to the following reasons: (1) the raspberry-like SbPt NPs exhibited versatile active exposed (110), (100), (101), and (012) facets as efficient HER catalysts, and (2) as confirmed by both the density functional theory (DFT) simulation and experimental results, the presence of Sb 3d subsurface broadened the Pt surface d-band, which caused synergistic effects on water splitting. In summary, synthesis of the new colloidal raspberry-like SbPt NPs is essential to elucidate the fundamental properties of the nanomaterial and nanostructure design. This study could facilitate the development of Pt-group materials that can be used as HER catalysts.