Controlled and cellulose eco-friendly synthesis and characterization of Bi₂O₂CO₃ quantum dot nanostructures (QDNSs)...

This work aimed to prepare solvent-free or green Bi₂O₂CO₃ for quantum dot nanostructures (QDNSs) based on cellulose as a stabilizer and green capping agent to sorafenib delivery for liver targeting. Because the walnut tree is one of the most abundant trees in Iran, it was tried to synthesize Bi₂O₂CO₃ QDNSs using a walnut skin extract. The saturation magnetization for Bi₂O₂CO₃ QDNSs was calculated to be 68.1. Also, the size of products was measured at around 60-80 nm with the Debye-Scherrer equation. Moreover, the morphology, functional groups, and crystallography of the Bi₂O₂CO₃ nanoparticles were investigated using atomic force microscopy, scanning electron microscopy, vibrating-sample magnetometer, and Uv-vis spectroscopy. The results demonstrated that Bi₂O₂CO₃ QDNSs have opto-magnetic properties and they can be suggested as the candidate materials for the sorafenib delivery on the liver tissue. The optical band gap estimated for Bi₂O₂CO₃ QDNSs was found to be red-shift from 3.22 eV. This study suggests the preparation of the Bi₂O₂CO₃ QDNSs based on cellulose as new opto-magnetic materials at different temperatures of 180 °C, 200 °C, 220 °C, and 240 °C for sorafenib delivery as a type of biological therapy drug.