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Relationship between the Transport Coefficients of Polar Substances and Entropy
Ivan Anashkin1, Sergey Dyakonov1, German Dyakonov1
1Chemical Process Engineering Department, Kazan National Research Technological University, Kazan 420063, Russia.
Abstract:
An expression is proposed that relates the transport properties of polar substances (diffusion coefficient, viscosity coefficient, and thermal conductivity coefficient) with entropy. To calculate the entropy, an equation of state with a good description of the properties in a wide region of the state is used. Comparison of calculations based on the proposed expressions with experimental data showed good agreement. A deviation exceeding 20% is observed only in the region near the critical point as well as at high pressures.
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