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Printable hexagonal boron nitride ionogels.

Woo Jin Hyun1, Lindsay E Chaney, Julia R Downing

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Summary
This summary is machine-generated.

Printable hexagonal boron nitride (hBN) ionogel inks were developed using exfoliated hBN nanoplatelets. These inks enable high-resolution printing of ionogels for flexible electronics applications.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Electrochemistry

Background:

  • Hexagonal boron nitride (hBN) offers excellent stability and robustness, making it suitable for ionogel matrices.
  • Existing hBN ionogels are limited to macroscopic applications, lacking compatibility with high-resolution printing.
  • Development of printable ionogel inks is crucial for advanced electronic applications.

Purpose of the Study:

  • To develop aerosol jet-printable ionogel inks using exfoliated hBN nanoplatelets.
  • To characterize the properties of the printed hBN ionogels.
  • To demonstrate the application of these ionogels in printed flexible electronics.

Main Methods:

  • Liquid-phase exfoliation of bulk hBN powders to produce hBN nanoplatelets.
  • Formulation of printable inks by combining hBN nanoplatelets, ionic liquid, and ethyl lactate.
  • Aerosol jet printing for fabricating ionogel patterns with controlled thickness and resolution.

Main Results:

  • Successfully formulated and printed hBN ionogel inks using aerosol jet printing.
  • Achieved high room-temperature ionic conductivity (>3 mS cm⁻¹) and storage modulus (>1 MPa) in printed hBN ionogels.
  • Demonstrated fully-printed thin-film transistors on polyimide films with operating voltages below 1 V.

Conclusions:

  • Aerosol jet-printable hBN ionogel inks were successfully developed.
  • The printed hBN ionogels exhibit excellent ionic conductivity and mechanical properties.
  • These findings confirm the potential of hBN ionogels for fabricating high-performance printed and flexible electronics.