Degradation of BTEXS with stable and pH-insensitive iron-manganese modified biochar from post pyrolysis

An efficient iron-manganese modified biochar (FMBC) was successfully synthesized as a heterogeneous Fenton-like catalyst through easy post-modification and applied for degradation of benzene, toluene, ethylbenzene, xylene isomers (ortho, para, and meta), and styrene (BTEXS) in the presence of H₂O₂. The catalyst was characterized by Brunauer-Emmett-Teller method, scanning electron microscopy, and X-ray photoelectron spectrometry. The effects of H₂O₂ concentration, FMBC dose, and initial pH on BTEXS degradation were also investigated. Results showed that degradation efficiency of FMBC for individual BTEXS varied from 83.05% to 94.12% in 3 h. Kinetic analysis showed that a first-order kinetic model with respect to BTEXS concentration could be used to explain the BTEXS degradation for FMBC/H₂O₂ system. The degradation reaction was more suitable in a wide pH range (3-10) than those in previous studies, thereby overcoming the low-efficiency problem of conventional Fenton reaction at high pH. Moreover, the doses of FMBC and H₂O₂ are a crucial factor affecting BTEXS degradation. Radical scavenger experiments revealed that ∙OH, ∙O₂^-, and ¹O₂ participated in the degradation process, and ∙OH was the major contributor. The synthesized catalyst is durable with stable BTEXS removal efficiency after seven consecutive cycles. The removal efficiency of BTEXS by FMBC in produced water reached 93.23% in 12 h, indicating FMBC has practical value.