Raney nickel coupled nascent hydrogen as a novel strategy for enhanced reduction of nitrate and nitrite

Raney nickel (R-Ni) is a cost-effective hydrogenation catalyst, and nascent hydrogen (Nas-H₂) generated in situ on the cathode trends to more reactive than commercial hydrogen (Com-H₂). In the present work, nitrate and nitrite (NO_X^-) reduction via R-Ni/Nas-H₂ catalytic system was investigated. The results show that hydrogenation of NO_X^- (C₀ = 3.0 mM) follows pseudo-first-order reaction kinetics with kinetic constants of 5.18 × 10^-2 min^-1 (NO₃^-) and 6.46 × 10^-2 min^-1 (NO₂^-). The saturation demand for Nas-H₂ is only 0.8 mL min^-1 at a fixed R-Ni dosage of 1.0 g L^-1. The experiments reveal that both Nas-H₂ and hydrogen adatoms (H_ads∗) can drive the reduction of NO_X^-. The improved reduction ratios of NO_X^- are attributed to two aspects: (1) the micro/nano-sized Nas-H₂ bubbles exhibits increased reactivity due to the fine dispersion of the hydrogen molecules; (2) the alkaline environment formed by the cathode positively maintain R-Ni activity, thus, Nas-H₂ bubbles were more readily activated to generate powerful H_ads∗. The results give insight into NO_X^- hydrogenation via introducing fine hydrogen resource, and can develop an efficient catalytic hydrogenation technique without noble metals.