Short-chain chlorinated paraffins in soils indicate landfills as local sources in the Tibetan Plateau

Background contamination levels of contemporary persistent organic pollutants (POPs) may be elevated due to local discharges, and hence it is of high importance to assess and monitor them in alpine and Polar Regions. This study investigated the role of waste disposal in the Tibetan plateau as the local source of short-chain chlorinated paraffins (SCCPs). SCCPs were determined in soils from the urban landfill and rural dumpsites, with a concentration range of 56.8-1348 ng/g dw. The gradient descent of SCCP levels from Lhasa landfill to the surrounding soils with increasing distances suggested a significant SCCP release from waste disposal. The transport pattern was well fitted by the Boltzmann equation after normalization in terms of soil organic carbon contents. Compared to the landfill cells closed in early years, the recently closed cells contained higher concentrations but lower proportions of the short-chain congener groups, likely reflecting the SCCP use history in Tibet. In open-burning dumpsites, higher SCCP levels and dominance of lighter congener groups indicates that such crude waste treatment process might cause an extra release of volatile SCCPs. This study elucidates local SCCP inputs to the background environment, and demonstrates that both urbanization and badly-managed landfill have been contributing to the presence of contemporary POPs in the Tibetan Plateau.