Mesoporous WO₃/TiO₂ spheres with tailored surface properties for concurrent solar photocatalysis and membrane...

The strategical integration of membrane water filtration with semiconductor photocatalysis presents a frontier in deep purification with a self-cleaning capability. However, the membrane fouling caused by the cake layer of the reclaimed TiO₂ nanoparticles is a key obstacle. Herein, mesoporous WO₃/TiO₂ spheres (∼450 nm in diameter) consisting of numerous self-assembled WO₃-decoated anatase TiO₂ nanocrystallites are successfully prepared via a facile wet-chemistry route. The decoration of monolayered WO₃ significantly affects the surface, photocatalytic, and optical properties of original mesoporous TiO₂ spheres. XRD and Raman analyses show the presence of monolayered WO₃ suppresses the crystal growth of TiO₂ during the calcination process, significantly improves the surface acidity, and causes an obvious red shift in absorption edge. These favorable textural properties, coupling the enhanced interfacial charge carrier separation, render mesoporous WO₃/TiO₂ spheres with a superior photocatalytic activity in degradation of methylene blue under UV, visible, and solar light irradiations. The optimal molar ratio of W/Ti is examined to 6%. The synthesized mesoporous WO₃/TiO₂ spheres also show much higher flux during membrane filtration in both dead-end and cross-flow modes, suggesting a promising photocatalyst for concurrent membrane filtration and solar photocatalysis.