Photocatalytic study of nanocomposite membrane modified by CeF3 catalyst for pharmaceutical wastewater treatment

Cerium fluoride (CeF₃) nanoparticles (NPs) were synthesized and applied in polysulfone (PS) membrane fabricated by phase inversion method. The produced nanocomposite membranes (PS/CeF₃) with different contents of CeF3 NPS (0.25%, 0.5%, 0.75% and 1% w/w) were used to treat pharmaceutical wastewaters. The membranes were characterized by FESEM, EDX, XRD, FTIR, porosity, and water contact angle analyses. Evaluation of the characteristics and performance of the nanocomposite membranes confirmed that utilizing photocatalytic CeF₃ NPs in membrane structure could effectively decompose organic contaminants in pharmaceutical wastewaters. It also improves the hydrophilicity and antifouling ability of membrane during filtration especially, in the presence of UV irradiation. The permeate flux of the PS membrane increased from 35.1 to 63.77 l/m²h by embedding 0.75% of CeF₃ NPs in membrane structure due to the porosity enhancement from 71.36-78.42% and the decrease in contact angle from 62.9º to 53.73º. Moreover, the flux decline of PS/CeF₃-0.75% membrane under UV irradiation was from 63.6 to 46.1 l/m²h that considerably lower than that of the neat PS membrane (from 34.7 to 4.9). On the other hand, the degradation efficiency of PS/CeF₃-0.75% membrane was more than 97%, and COD removed was more than 65% while they were 75% and 31%, respectively for the nascent PS membrane. Therefore, applying the appropriate amount of CeF₃ NPs in PS membranes not only greatly increased the permeate flux but also significantly enhanced the degradation efficiency and COD removal. This indicates that nanocomposite membranes can be confidently applied for pharmaceutical wastewater treatment UV irradiation.