Influence of Synthesis Methods on the High-Efficiency Removal of Cr(VI) from Aqueous Solution by Fe-Modified Magnetic...

Fe-modified biochars have been widely used in removal of Cr(VI) from water due to the resulting modified surface functional groups and magnetization property. However, few studies have synthetically investigated modification methods and synthesis parameters on the improvement of the removal efficiency of Cr(VI) by Fe-modified biochars. Herein, 10 types of corn straw-based magnetic biochars were produced using pre-modification and post-modification methods with various modifier ratios, and the highest heating temperature (HHT). Cr(VI) removal results suggest that the removal efficiency of pre-modified biochars ranged from 50.7 to 98.6%, which was much higher than that of post-modified (6.6-21.6%) and unmodified biochars (0.4-7.6%). The effect of synthesis methods on Cr(VI) adsorption was in the following order: Fe-modification method > modifier ratio > HHT. The adsorption kinetics and isotherm results of three types of pre-modified biochars were well fitted with the pseudo-second-order model (R ² > 0.99) and the Langmuir adsorption model (R ² > 0.99), respectively, indicating the surface homogeneity of the pre-modified biochars and unilayer chemisorptions of Cr(VI). Characterization results show that iron oxides or zerovalent iron particles were successfully deposited onto the surface of biochars and magnetism was introduced. A good Pearson correlation (r = -0.9694) between the removal efficiency and pH value in modified biochar suggests that the lower pH value may offer more positive charges and promote electrostatic attraction. Therefore, the dominant mechanism for enhanced Cr(VI) adsorption on pre-modified biochar was electrostatic attraction, resulting from its distinguished acidity nature. Our findings provide new insights into the high-efficiency removal of Cr(VI) onto Fe-modified magnetic biochars and will benefit future design of more efficient magnetic biochars.