Inclusion and Charge Transfer Interaction of a Multi-Redox Active 1,3,5-Triazine Derivative by Cucurbit[7,8]urils
1Department of Chemistry and Biochemistry, California State University Dominguez Hills, Carson, California 90747, United States.
Abstract:
The redox active 1,3,5-triazine derivative (MPT) was used as a guest to study host-guest, charge transfer interaction with CB[7,8] in water. The multi-redox active MPT undergoes four chemically and electrochemically reversible one electron redox states in organic media, but in water, the fourth redox state shows an unstable nature. As a guest, the host-guest interaction of MPT was studied with two macrocyclic cucurbit[7,8]uril (CB[7,8]) hosts in water; resulting supramolecular complexes were characterized by NMR, ESI-MS, UV-vis, ITC, and cyclic voltammetric studies.
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