Health risk assessment of construction workers from trace metals in PM_2.5 from Kolkata, India

Construction activities have long been recognized as a pertinent source of PM_2.5 though limited information exists regarding chemical characteristics of aerosols generated during building demolition/construction. A comprehensive investigation was carried out to assess the physical (SEM analysis) and chemical (ICP MS analysis) properties of PM_2.5 in a building demolition and construction site and compared with background. Average concentrations of PM_2.5 at both the sites exceeded the National Ambient Air Quality Standards (NAAQS). Overall trend of the total metal concentrations of PM_2.5 followed the order of (Na, Ca, Al, Mg, Fe, Zn) > (Ti, Sr, Cd, Ba, Pb, V, Cr, Mn, Co, Ni, Cu) in both the sites. Sr, Ba, Mg, Zn, Ti, Cd, Al, Cr, Fe, Co, Mn, V, Ni, Ca, and Zn showed a ∼1.3-3.0 fold increase, and Pb showed the highest increase of almost >3.5 times when compared to the background concentrations. Health risk estimates based on the bio-available concentration of metals indicated that hazard quotient (HQ) values for non-carcinogenic metals were within the prescribed limit (HQ ≤ 1). However, the excess lifetime cancer risk (ELCR) for the carcinogenic metals Pb, Ni, Cd, and Cr(VI) were higher than the guideline limits of USEPA.