Low-Temperature Synthesis of Monolithic Titanium Carbide/Carbon Composite Aerogel

Resorcinol-formaldehyde/titanium dioxide composite (RF/TiO₂) gel was prepared simultaneously by acid catalysis and then dried to aerogel with supercritical fluid CO₂. The carbon/titanium dioxide aerogel was obtained by carbonization and then converted to nanoporous titanium carbide/carbon composite aerogel via 800 °C magnesiothermic catalysis. Meanwhile, the evolution of the samples in different stages was characterized by X-ray diffraction (XRD), an energy-dispersive X-ray (EDX) spectrometer, a scanning electron microscope (SEM), a transmission electron microscope (TEM) and specific surface area analysis (BET). The results showed that the final product was nanoporous TiC/C composite aerogel with a low apparent density of 339.5 mg/cm³ and a high specific surface area of 459.5 m²/g. Comparing to C aerogel, it could also be considered as one type of highly potential material with efficient photothermal conversion. The idea of converting oxide-carbon composite into titanium carbide via the confining template and low-temperature magnesiothermic catalysis may provide new sight to the synthesis of novel nanoscale carbide materials.