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Published on: February 10, 2020
Tunable Non-linear Refraction Properties and Ultrafast Excited State Dynamics of Dicyanomethylene Dihydrofuran
Linpo Yang1, Zhongguo Li2, Taihui Wei1
1Department of Physics, Harbin Institute of Technology, Harbin, China.
Abstract:
The third order non-linear optical response of a dicyanomethylene dihydrofuran compound (DCDHF-2V) was investigated using a Z-scan technique in picosecond and nanosecond time regimes. The results show that DCDHF-2V has excellent excited state non-linear refraction properties on both time regimes, and the non-linear refraction index is also solvent-dependent in the nanosecond regime. The excited state relaxation dynamics of DCDHF-2V were demystified via femtosecond transient absorption spectroscopy. The TA spectra reveal that the solvent viscosities have a substantial impact on the excited state relaxation of DCDHF-2V. The exotic photophysical phenomena in DCDHF-2V reported herein can shed new light on future development of small organic non-linear optical materials with large non-linear coefficients and fast response.
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