Electrochemical Stimulation of Water-Oil Interfaces by Nonionic-Cationic Block Copolymer Systems

Variable interfacial tension could be desirable for many applications. Beyond classical stimuli like temperature, we introduce an electrochemical approach employing polymers. Hence, aqueous solutions of the nonionic-cationic block copolymer poly(ethylene oxide)₁₁₄-b-poly{[2-(methacryloyloxy)ethyl]diisopropylmethylammonium chloride}₁₇₁ (i.e., PEO₁₁₄-b-PDPAEMA₁₇₁ with a quaternized poly(diisopropylaminoethyl methacrylate) block) were investigated by emerging drop measurements and dynamic light scattering, analyzing the PEO₁₁₄-b-qPDPAEMA₁₇₁ impact on the interfacial tension between water and n-decane and its micellar formation in the aqueous bulk phase. Potassium hexacyanoferrates (HCFs) were used as electroactive complexants for the charged block, which convert the bishydrophilic copolymer into amphiphilic species. Interestingly, ferricyanides ([Fe(CN)₆]^3-) act as stronger complexants than ferrocyanides ([Fe(CN)₆]^4-), leading to an insoluble qPDPAEMA block in the presence of ferricyanides. Hence, bulk micellization was demonstrated by light scattering. Due to their addressability, in situ redox experiments were performed to trace the interfacial tension under electrochemical control, directly utilizing a drop shape analyzer. Here, the open-circuit potential (OCP) was changed by electrolysis to vary the ratio between ferricyanides and ferrocyanides in the aqueous solution. While a chemical oxidation/reduction is feasible, also an electrochemical oxidation leads to a significant change in the interfacial tension properties. In contrast, a corresponding electrochemical reduction showed only a slight response after converting ferricyanides to ferrocyanides. Atomic force microscopy (AFM) images of the liquid/liquid interface transferred to a solid substrate showed particles that are in accordance with the diameter from light scattering experiments of the bulk phase. In conclusion, the present results could be an important step toward economic switching of interfaces suitable, e.g., for emulsion breakage.