Tailoring the Pore Size and Chemistry of Ionic Ultramicroporous Polymers for Trace Sulfur Dioxide Capture with High...

Here we demonstrate the deep removal of SO₂ with high uptake capacity (1.55 mmol g^-1 ) and record SO₂ /CO₂ selectivity (>5000) at ultra-low pressure of 0.002 bar, using ionic ultramicroporous polymers (IUPs) with high density of basic anions. The successful construction of uniform ultramicropores via polymerizing ionic monomers into IUPs enables the fully exploitation of the selective anionic sites. Notably, the aperture size and surface chemistry of IUPs can be finely tuned by adjusting the branched structure of ionic monomers, which play critical roles in excluding CH₄ and N₂ , as well as reducing the coadsorption of CO₂ . The swelling property of IUPs with adsorption of SO₂ contributed to the high SO₂ uptake capacity and high separation selectivity. Systematic investigations including static gas adsorption, dynamic breakthrough experiments, stability tests and modeling studies confirmed the efficient performance of IUPs for trace SO₂ capture.