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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Ring-forming transformation associated with hydrazone changes of hexadecanuclear dysprosium phosphonates

Haiquan Tian1, Fu-Ping Huang2, Yongfei Li1

  • 1Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China. tianhaiquan@lcu.edu.cn.

Dalton Transactions (Cambridge, England : 2003)
|January 4, 2021
PubMed
Summary

Researchers synthesized novel dysprosium-phosphonate coordination clusters by altering hydrazone ligands. A structural transformation from ellipsoidal to square motifs was observed, leading to similar single-molecule magnet behaviors in the new complexes.

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