Efficient removal of selenate in water by cationic poly(allyltrimethylammonium) grafted chitosan and biochar...

The discovery of cheap and eco-friendly functional materials for the removal of anionic heavy metal ions is still challenging in the treatment of heavy metal-contaminated water. Herein, a new poly(allyltrimethylammonium) grafted chitosan and biochar composite (PATMAC-CTS-BC) was introduced for the removal of selenate (SeO₄^2-) in water. Results suggest that the PATMAC-CTS-BC showed a rapid removal of SeO₄^2- with efficiency of >97% within 10 min and it followed a pseudo-second-order model. High capacity of SeO₄^2- adsorption by the composite was achieved, with maximum value of 98.99 mg g^-1 based on Langmuir model, considerably higher than most of reported adsorbents. The thermodynamic results reflected the spontaneous and exothermic nature of SeO₄^2- adsorption onto the composite. The composite could be applied at a wide initial pH range (2-10) with high removal efficiency of SeO₄^2- because of permanent positive charges of quaternary ammonium groups (=N⁺-). The removal mechanisms of SeO₄^2- were mainly attributed to electrostatic interactions with =N⁺- and protonated -NH₃⁺ groups, and redox-complexation interactions with -NH₂, -NH-, and -OH groups. Besides SeO₄^2-, the hexavalent chromium (Cr₂O₇^2-) was considered as example to further demonstrate the anion removal capability of cationic hydrogel-BC composite. The study outcomes open up new opportunities to efficiently remove anionic heavy metal ions (e.g., SeO₄^2- and Cr₂O₇^2-) in water using these materials.