Related Experiment Video
Updated: Nov 22, 2025

Millifluidics for Chemical Synthesis and Time-resolved Mechanistic Studies
Published on: November 27, 2013
Highly Efficient Silver Catalyst Supported by a Spherical Covalent Organic Framework for the Continuous Reduction of
Ning Wang1,2,3, Fushuai Wang4, Fei Pan1,3
1CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Research Center for Coastal Environmental Engineering and Technology of Shandong Province, Shandong Key Laboratory of Coastal Environmental Processes, YICCAS, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, Shandong 264003, P. R. China.
Abstract:
Developing new materials and novel technologies for the highly efficient treatment of toxic organic pollutants is highly desirable. Chemical reduction based on heterogeneous substrate/noble metal catalysts and the reducing agent NaBH4 has become an effective method in recent years. Here, a spherical covalent organic framework (SCOF) was designed to provide basic sites for Ag ions, by which small Ag NPs were immobilized on the SCOF to form Ag NPs@SCOF microspheres. The prepared microspheres exhibited a high catalytic reduction ability toward 4-nitrophenol (4-NP). An optimized permeation flux of 2000 L m-2 h-1 (LMH) and a more than 99% 4-NP reduction efficiency were obtained with flow-through experiments, which are far better than the reported results (below 200 LMH). Moreover, the microspheres could maintain stable catalytic performance under a continuous flow-through process. Our work provides an efficient material and technology that can be applied to easily treat toxic organic pollutants.
Related Concept Videos
Preparation of Amines: Reduction of Oximes and Nitro Compounds
Though catalytic hydrogenation can reduce nitrobenzenes, the reduction is nonselective in the presence of other functional groups. For instance, if nitrobenzene contains an aldehyde group,...
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism
Electrophilic Aromatic Substitution: Nitration of Benzene
Oxidation of Phenols to Quinones
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox...
meta-Directing Deactivators: –NO2, –CN, –CHO, –⁠CO2R, –COR, –CO2H
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
