Chemically synthesized Sb₂S₃ hollow-spheres for significantly fast and reliable visible light driven dye...

Sb₂S₃ hollow-spheres in powder form were synthesized through a facile chemical route. The synthesized material was found to have notably high specific surface area. After annealing it showed broadband absorption of light within the visible region. The valance band and conduction band of the synthesized semiconductor were also positioned appropriately (w.r.t NHE) so that the required redox reactions with water in presence of the photogenerated excitons are facilitated. These factors make it a suitable candidate for photocatalytic applications towards the degradation of dye based water pollutants. The synthesized material was established through systematic structural, compositional and optical characterizations. The photocatalytic efficacy toward the degradation of cationic, anionic and neutral dyes has been studied and the best degradation efficiency of 99.72% within 20 min has been achieved at a rate of 0.2920/min, which is significantly higher than many previous reports. Reusability, one of the major factors for the practical application of a catalyst, has also been studied in detail by investigating the probable changes in structural properties as well as in performance after several cycles of photodegradation. The reliability studies yielded encouraging results even after 50th cycle of photodegradation. The effect of catalyst loading on the photodegradation efficacy has also been studied.