Coupling CsPbBr₃ Quantum Dots with Covalent Triazine Frameworks for Visible-Light-Driven CO₂ Reduction

Photocatalytic reduction of CO₂ into value-added chemical fuels is an appealing approach to address energy crisis and global warming. CsPbBr₃ quantum dots (QDs) are good candidates for CO₂ reduction because of their excellent photoelectric properties, including high molar extinction coefficient, low exciton binding energy, and defect tolerance. However, the pristine CsPbBr₃ QDs generally have low photocatalytic performance mainly due to dominant charge recombination and lack of efficient catalytic sites for CO₂ adsorption/activation. Herein, we report a new photocatalytic system, in which CsPbBr₃ QDs are coupled with covalent triazine frameworks (CTFs) for visible-light-driven CO₂ reduction. In this hybrid photocatalytic system, the robust triazine rings and periodical pore structures of CTFs promote the charge separation in CsPbBr₃ and endow them with strong CO₂ adsorption/activation capacity. The resulting photocatalytic system exhibits excellent photocatalytic activity towards CO₂ reduction. This work presents a new photocatalytic system based on CTFs and perovskite QDs for visible-light-driven CO₂ reduction, which highlights the potential of perovskite-based photocatalysts for solar fuel applications.