Phototransformation of three polychlorinated naphthalenes on surface of atmospheric particulate matter

Polychlorinated naphthalenes (PCNs) are a new class of persistent organic pollutants. Photoconversion is an important pathway for their transformation in the environment. In this work, silica gel was used to simulate atmospheric mineral particles, and the photochemical reaction of three PCNs 1-chloronaphthalene (CN-1), 2-chloronaphthalene (CN-2) and 2,3-dichloronaphthalene (CN-10)) on silica gel surface was studied under the irradiation of high-pressure mercury lamp, the phototransformation intermediates and pathways of PCNs were investigated, effects of reactive oxygen species (ROS, ·OH, ¹O₂ and O₂^-·) were proved by free radical scavenging method and the effects of co-existing components (water, inorganic ions and fulvic acid) were examined. The results showed that all the three PCNs could be photochemical degraded on silica gel surface. The order of the apparent rate constants was CN-2 ≈ CN-1 > CN-10. ROS accelerated the photochemical reaction. The three PCNs didn't produce completely identical photoproducts, but all underwent a series of reactions such as reductive dechlorination, hydroxylation, oxidation, decarboxylation and ring opening. In addition, for the photoconversion of CN-1, the presence of water, NO₃^- or fulvic acid all promoted the photochemical transformation, while the presence of Cu²⁺ had an inhibitory effect.