Europium(III) complex fluorescent sensor for dual channel recognition of Sn²⁺ and Cu²⁺ ions in water

A new europium(III) complex Eu(tta)₃L₁ (1a) (L₁ = (2-(3,5-dimethoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), tta = 2-thenoyltrifluoroacetone) has been prepared and synthesized. The structure of complex was completely determined by several different analytical techniques including single-crystal X-ray diffraction, ¹H and ¹³C NMR. The crystal structure of the complex 1a belonged to monoclinic system with the space group P2₁/n. Its fluorescent properties were systematically studied in details by adding different metal ions in deionized water. Upon addition of Sn²⁺, its fluorescence intensity was strengthened and centered at 460 nm. And when Cu²⁺ was added, its fluorescence emission intensity was quenched quickly. The LODs for Sn²⁺ and Cu²⁺ were calculated to be 4.52 × 10^-7 mol L^-1 and 1.11 × 10^-7 mol L^-1, respectively. Furthermore, this sensor was successfully employed to monitor Sn²⁺ and Cu²⁺ in practical samples.