Thermocatalytic hydrogen peroxide generation and environmental disinfection by Bi₂Te₃ nanoplates

The highly reactive nature of reactive oxygen species (ROS) is the basis for widespread use in environmental and health-related fields. Conventionally, there are only two kinds of catalysts used for ROS generation: photocatalysts and piezocatalysts. However, their usage has been limited due to various environmental and physical factors. To address this problem, herein, we report thermoelectric materials, such as Bi₂Te₃, Sb₂Te₃, and PbTe, as thermocatalysts which can produce hydrogen peroxide (H₂O₂) under a small surrounding temperature difference. Being the most prevalent environmental factors in daily life, temperature and related thermal effects have tremendous potential for practical applications. To increase the practicality in everyday life, bismuth telluride nanoplates (Bi₂Te₃ NPs), serving as an efficient thermocatalyst, are coated on a carbon fiber fabric (Bi₂Te₃@CFF) to develop a thermocatalytic filter with antibacterial function. Temperature difference induced H₂O₂ generation by thermocatalysts results in the oxidative damage of bacteria, which makes thermocatalysts highly promising for disinfection applications. Antibacterial activity as high as 95% is achieved only by the treatment of low-temperature difference cycles. The current work highlights the horizon-shifting impacts of thermoelectric materials for real-time purification and antibacterial applications.