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Updated: Nov 21, 2025

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Passing the framework skeleton and properties of coordination materials onto organic framework materials
Xuan Wang1, Ming-Jie Dong, Kai Chen
1State Key Laboratory of Silicon Materials, Department of Chemistry, Zhejiang University, Hangzhou, 310027, P. R. China. cdwu@zju.edu.cn.
Abstract:
A practically applicable strategy for transforming fragile metal-organic frameworks (MOFs) into highly stable and ordered organic framework materials (OFMs) is developed by replacing the labile coordination bonds in MOFs with stable covalent bonds in OFMs, which exhibit hypothetically approximated topology, porosity and properties of the parent MOFs by merging the advantages of MOFs and porous organic materials, thus providing a general pathway for the synthesis of highly ordered OFMs with merged advantages of MOFs and organic polymers.
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Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...

