A Bio-Inspired Nanotubular Na₂MoO₄/TiO₂ Composite as a High-Performance Anodic Material for Lithium-Ion Batteries

A train of bio-inspired nanotubular Na₂MoO₄/TiO₂ composites were synthesized by using a natural cellulose substance (e.g., commercial ordinary filter paper) as the structural template. The TiO₂ gel films were coated on the cellulose nanofiber surfaces via a sol-gel method firstly, followed with the deposition of the poly(diallyldimethylammonium chloride)/Na₂MoO₄ (PDDA/Na₂MoO₄) bi-layers several times, through the layer-by-layer self-assembly route, yielding the (PDDA/Na₂MoO₄)_n/TiO₂-gel/cellulose composite, which was calcined in air to give various Na₂MoO₄/TiO₂ nanocomposites containing different Na₂MoO₄ contents (15.4, 24.1, and 41.4%). The resultant nanocomposites all inherited the three-dimensionally porous network structure of the premier cellulose substance, which were formed by hierarchical TiO₂ nanotubes anchored with the Na₂MoO₄ layers. When employed as anodic materials for lithium-ion batteries, those Na₂MoO₄/TiO₂ nanocomposites exhibited promoted electrochemical performances in comparison with the Na₂MoO₄ powder and pure TiO₂ nanotubes, which was resulted from the high capacity of the Na₂MoO₄ component and the buffering effects of the TiO₂ nanotubes. Among all the nanotubular Na₂MoO₄/TiO₂ composites, the one with a Na₂MoO₄ content of 41.4% showed the best electrochemical properties, such as the cycling stability with a capacity of 180.22 mAh g^-1 after 200 charge/discharge cycles (current density: 100 mA g^-1) and the optimal rate capability.