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Updated: Nov 21, 2025
Preparation, Purification, and Characterization of Lanthanide Complexes for Use as Contrast Agents for Magnetic Resonance Imaging
Published on: July 21, 2011
Structural and magnetic studies of mononuclear lanthanide complexes derived from N-rich chiral Schiff bases
E Pilichos1, M Font-Bardia2, A Escuer1
1Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotecnology, Universitat de Barcelona, Marti i Franques 1-11, Barcelona-08028, Spain. albert.escuer@qi.ub.edu.
Abstract:
A new family of mononuclear lanthanide complexes with the formula [CeIII(L)(NO3)3(MeOH)] (1) and [LnIII(L)(NO3)3]·MeOH where Ln = Gd (2) or Dy (3) and L = N,N'-bis(pyridin-2-ylmethylene)cyclohexane-1,2-diamine has been obtained with the use of enantiomerically pure Schiff bases. Dynamic magnetic studies indicate that 1-3 present field-induced slow relaxation of the magnetization and their response has been compared with the magnetically diluted complexes 2d and 3d. Structural studies have been carried out by single crystal X-ray and powder diffraction.
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