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Ferromagnetism01:31

Ferromagnetism

2.8K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR01:15

¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR

1.4K
The axial and equatorial protons in cyclohexane can be distinguished by performing a variable-temperature NMR experiment. In this process, except for one proton, the remaining eleven protons are replaced by deuterium. The deuterium substitution avoids the possible peak splitting caused by the spin-spin coupling between the adjacent protons. The remaining proton flips between the axial and equatorial positions.
1.4K
Atomic Spectroscopy: Effects of Temperature01:27

Atomic Spectroscopy: Effects of Temperature

700
Atomization, converting samples into gas-phase atoms and ions, is essential for atomic spectroscopy. The flame temperature required for atomization affects the efficiency of the atomic spectroscopic methods by increasing the atomization efficiency and the relative population of the excited and ground states.
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature...
700
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

19.2K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
19.2K
Magnetic Susceptibility and Permeability01:31

Magnetic Susceptibility and Permeability

1.9K
In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
1.9K
Paramagnetism01:30

Paramagnetism

2.9K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.9K

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Updated: Nov 20, 2025

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
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Temperature dependent89Y NMR study on multiferroic YCrO3.

Ashish Kumar Mall1, A K Pramanik1

  • 1School of Physical Sciences, Jawaharlal Nehru University, New Delhi - 110067, India.

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|January 19, 2021
PubMed
Summary

This study uses 89Y Nuclear Magnetic Resonance (NMR) to investigate magnetic transitions in Yttrium Chromium Oxide (YCrO3). The research reveals insights into antiferromagnetic spin fluctuations and relaxation dynamics near the Neel temperature.

Keywords:
magnetic ordernuclear magnetic resonancerelaxation

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Area of Science:

  • Solid State Physics
  • Materials Science
  • Magnetism

Background:

  • Yttrium Chromium Oxide (YCrO3) is a material exhibiting complex magnetic properties.
  • Understanding magnetic transitions at a microscopic level is crucial for materials science applications.

Purpose of the Study:

  • To investigate the magnetic transition in YCrO3 using 89Y Nuclear Magnetic Resonance (NMR).
  • To study magnetism and relaxation times across the paramagnetic to antiferromagnetic transition.

Main Methods:

  • Temperature-dependent 89Y NMR measurements were performed on polycrystalline YCrO3.
  • Analysis included NMR peak width, shift, intensity, and spin-lattice relaxation rates (1/T1).

Main Results:

  • A magnetic transition (T_N ≈ 141 K) was identified, marked by changes in NMR parameters.
  • Broadening of NMR peaks indicates internal magnetic fields, while spin-lattice relaxation rates reveal magnetic phase transition and low-energy spin fluctuations.
  • Knight shift and 1/TT1 correlate linearly with bulk susceptibility, suggesting antiferromagnetic spin fluctuations.

Conclusions:

  • The study confirms the magnetic origin of the phase transition in YCrO3 due to Cr3+ ions.
  • NMR measurements provide microscopic insights into antiferromagnetic spin fluctuations and relaxation dynamics in YCrO3.