Luminescent PMMA Films and PMMA@SiO₂ Nanoparticles with Embedded Ln³⁺ Complexes for Highly Sensitive Optical...

In recent years, luminescent materials doped with Ln³⁺ ions have attracted much attention for their application as optical thermometers based on both downshifting and upconversion processes. This study presents research done on the development of highly sensitive optical thermometers in the physiological temperature range based on poly(methyl methacrylate) (PMMA) films doped with two series of visible Ln³⁺ complexes (Ln³⁺ =Tb³⁺ , Eu³⁺ , and Sm³⁺ ) and SiO₂ nanoparticles (NPs) coated with these PMMA films. The best performing PMMA film doped with Tb³⁺ and Eu³⁺ complexes was the PMMA[TbEuL₁ tppo]1 film (L₁ =4,4,4-trifluoro-1-phenyl-1,3-butadionate; tppo=triphenylphosphine oxide), which showed good temperature sensing of S_r =4.21 % K^-1 at 313 K, whereas for the PMMA films doped with Tb³⁺ and Sm³⁺ complexes the best performing was the PMMA[TbSmL₂ tppo]3 film (L₂ =4,4,4-trifluoro-1-(4-chlorophenyl)-1,3-butadionate), with S_r =3.64 % K^-1 at 313 K. Additionally, SiO₂ NPs coated with the best performing films from each of the series of PMMA films (Tb-Eu and Tb-Sm) and their temperature-sensing properties were studied in water, showing excellent performance in the physiological temperature range (PMMA[TbEuL₁ tppo]1@SiO₂ : S_r =3.84 % °C at 20 °C; PMMA[TbSmL₂ tppo]3@SiO₂ : S_r =3.27 % °C at 20 °C) and the toxicity of these nanoparticles on human cells was studied, showing that they were nontoxic.