Recovery of N₂O: Energy-Efficient and Structure-Driven Clathrate-Based Greenhouse Gas Separation

N₂O has 300 times more global warming potential than CO₂ and is also one of the main stratospheric ozone-depleting substances emitted by human activities such as agriculture, industry, and the combustion of fossil fuels and solid waste. We present here an energy-efficient clathrate-based greenhouse gas-separation (CBGS) technology that can operate at room temperature for selectively recovering N₂O from gas mixtures. Clathrate formation between α-form/β-form hydroquinone (α-HQ/β-HQ) and gas mixtures reveals guest-specific and structure-driven selectivity, revealing the preferential capture of N₂O in β-HQ and the molecular sieving characteristics of α-HQ. With a maximum gas storage capacity and cage occupancy of 54.1 cm³ g^-1 and 0.86, respectively, HQ clathrate compounds including N₂O are stable at room temperature and atmospheric pressure and thus can be easily synthesized, treated, and recycled via commercial CBGS processes. High selectivity for N₂O recovery was observed during β-HQ clathrate formation from N₂O/N₂ gas mixtures with N₂O concentrations exceeding 20%, whereas α-HQ traps only N₂ molecules from gas mixtures. Full characterization using X-ray diffraction, scanning electron microscopy, Raman spectroscopy, solid-state nuclear magnetic resonance, and compositional analysis and the formation kinetics of HQ clathrates was conducted to verify the peculiar selectivity behavior and to design the conceptual CBGS process. These results provide a new playground on which to tailor host-guest materials and develop commercial processes for the recovery and/or sequestration of greenhouse gases.