A facile method for the phosphorylation of cellulosic fabric via atmospheric pressure plasma

Green chemistry approach for phosphorylation of cellulose, under atmospheric pressure plasma was investigated and compared with conventional thermal method. The attachment of the phosphate groups was evaluated by ³¹P and ¹³C solid state NMR spectroscopy and XPS. The thermal method led to the formation of monophosphate of cellulose along with a side product of polymerized phosphate, whereas the plasma method produced only the monophosphate, without any side products. Unlike with the thermal treatment, the appearance and the mechanical properties of the viscose fabric remained nearly same after the plasma treatment. Also, the dyeability of the plasma modified fabric remained unchanged, whereas it decreased significantly in the thermally modified fabric. The amount of phosphate quantified by phosphomolybdate assay was found to be 2.88 ± 0.06 and 4.09 ± 0.19 % in the plasma and the thermal methods, respectively. This method has the potential to replace the existing methods of phosphorylation of cellulose.