Nano-MoO₂ activates peroxymonosulfate for the degradation of PAH derivatives

The rapid and efficient degradation of polycyclic aromatic hydrocarbon (PAH) derivatives with toxicological properties remains a substantial challenge. In this study, a cost-effective and eco-friendly catalyst, nano-MoO₂ (0.05 g L^-1), exhibited excellent performance in activating 4.0 mmol L^-1 peroxymonosulfate (PMS) for the degradation of naphthalene derivatives with 1 mg L^-1 in aqueous systems; these derivatives include 1-methylnaphthalene, 1-nitronaphthalene, 1-chloronaphthalene, 1-naphthylamine and 1-naphthol, with high degradation rates of 87.52%, 86.23%, 97.87%, 99.74%, and 77.16%. Nano-MoO₂ acts as an electron donor by transferring an electron causing O-O bond of PMS to cleave producing SO₄^·-, and later ^·OH. Electron paramagnetic resonance (EPR) analysis combined with free radical quenching research indicated that SO₄^·- and ^·OH dominated the degradation of naphthalene derivatives, and O₂^·- and ¹O₂ participated in the processes. X-ray photoelectron spectroscopy (XPS) revealed the transformation of Mo(IV) to Mo(V) and Mo(VI), which suggested that the activation process proceeded via electron transfer from nano-MoO₂ to PMS. The applicability of the nano-MoO₂/PMS system in influencing parameters and stability was explored. The degradation pathways were primarily elucidated for each naphthalene derivative based on the intermediates identified in the systems. The -CH₃, -NO₂, -Cl, -OH substituents increased the positive electrostatic potential (ESP) on the molecular surface of 1-methylnaphthalene, 1-nitronaphthalene, 1-chloronaphthalene, and 1-naphthol, which reduced the electrophilic reaction and electron transfer between the reactive species and pollutants, leading to a lower degradation rate of naphthalene derivatives than the parent compound. However, the effect of -NH₂ substituents is the opposite. These findings suggest that nano-MoO₂ may aid as a novel catalyst in the future remediation of environments polluted with PAH derivatives.